Yeah i think its definitely pssible to overtrain while you are on cycle, and i think you are. I am a high volume trainer mysel but not to the degree you are.
I think 20 sets on chest is too much all you need is a flat and incline press and some type of flye. You must be doing a lot of exercises that are quite similiar like incline bench and incline dumbell press. I would cut that back to about 12 sets for example.
4 Sets incline bench
4 sets flat dumbell press
4 sets incline flyes
I also do 20 sets for back but this is fine IMO as there is so much area back there to cover from traps to erectors.
20 sers for shoulders is also far to much and i would cut back on the arms as well.